Co2 operate at 10.6uM to a fibers 1064nM… Both are in the IR spectrum. A Nd:YAG laser operates at the same frequency of a fiber. Yag lasers are what some of the non-fiber 1064nM lasers use for IR.
Fiber doesn’t work well on natural materials or some others, including acrylic, glass, wood, hot dogs, bread and baloney. Acrylic is man made, but it isn’t useful with a fiber… maybe with a colored acrylic, but it’s back to the same issue as a visible diode.