Still working on a couple of issues engraving glass with 10watt Diode laser. Using black tempera paint. I ran a material test and this seems to be case on them all…
When the job is finished, there is an amber colored coating in outside of the engraving (back side.)
What is the surface underneath your glass? I get something like that when I engrave the backside of mirrors and I don’t have a clean surface under it. Especially if it is a wood surface. I believe it is off gassing from the wood. Sap and moisture being driven out.
Try your test again with a white, shiny paper under it. I bet it will come out clean. Printer paper may be enough, but the more gloss the better result.
Yes, coated side up. The paint has to escape as it is get ablated by the laser. Much better to let if dissipate into your air extractor than to get trapped under and then stick to your piece of glass.
If it’s epoxy or a fiberglass of some kind it could very well be toxic debris. If I try to cut F4 type pcb with my fiber, it has a difficult time getting through the fiberglass and looks very similar.