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The Home command, when issued, tells your machine to seek the limit switches to establish a repeatable origin. Without limit switches and homing enabled, issuing the home command will give you an error.
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Read https://github.com/gnea/grbl/wiki/Grbl-v1.1-Configuration#100-101-and-102--xyz-stepsmm
and How are steps calibrated?
You can edit the actual step length settings in the Edit => Machine Settings dialog in LightBurn.